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glucan(x) glucan(n-2) glucan(n) D-maltose ADP branched glucan ADP-glucose glucan(y) P (glucan)n+1 linear glucan D-glucose (glucan)n-1 2.4.1.1 | phosphorylase 3.2.1.20 | alpha-glucosidase 3.2.1.41 | pullulanase 3.2.1.1 | alpha-amylase 3.2.1.2 | beta-amylase 2.4.1.18 | 1,4-alpha-glucan branching enzyme 2.4.1.21 | starch synthase